Methods and Applications of Cycloaddition Reactions in Organic Syntheses
Nagatoshi Nishiwaki (Editor)
ISBN: 978-1-118-29988-3
Hardcover / 672 pages / January 2014
US $195.00
有機合成で頻繁に用いられる環化付加反応は、長い研究史を持つにもかかわらず、近年になっても急速な発展を遂げているため、最新の成果を常に把握するのは容易ではありません。
そういった化学者のニーズに応えるため編集された本書は、主要な環化付加反応と、複素環化合物・天然化合物・機能性分子の合成などへの応用について各章で詳述するものです。環化付加反応全体を網羅し、最新の知識をまとめた本としては現在類書が見当たらず、本書は有機合成化学・創薬・材料科学分野の研究者・学生に有益な参考書となるはずです。
本書の編者は高知工科大・西脇 永敏教授で、日本および各国の有力な化学者が各章を執筆しています。
本書の目次
PART I [2+1] CYCLOADDITION
1 [2+1]-TYPE CYCLOPROPANATION REACTIONS
Akio Kamimura
2 N1 UNIT TRANSFER REACTION TO C-C DOUBLE BONDS
Satoshi Minakata, Youhei Takeda, and Kensuke Kiyokawa
PART II [2+2] CYCLOADDITION
3 LEWIS BASE CATALYZED ASYMMETRIC FORMAL [2þ2] CYCLOADDITIONS
Andrew D. Smith, James Douglas, Louis C. Morrill, and Edward Richmond
PART III [2+2] AND [4+2]/[2+2] CYCLOADDITION
4 CATALYTIC [2þ2] CYCLOADDITION OF SILYL ENOL ETHERS
Yosuke Yamaoka and Kiyosei Takasu
PART IV [3+2] CYCLOADDITION
5 [3þ2] CYCLOADDITION OF a,b-UNSATURATED METAL-CARBENE COMPLEXES
Ryukichi Takagi and Manabu Abe
6 GEOMETRY-CONTROLLED CYCLOADDITION OF C-ALKOXYCARBONYL NITRONES: SYNTHETIC STUDIES ON NONPROTEINOGENIC AMINO ACIDS
Osamu Tamura
7 RECENT ADVANCES IN CATALYTIC ASYMMETRIC 1,3-DIPOLAR CYCLOADDITIONS OF AZOMETHINE IMINES, NITRILE OXIDES, DIAZOALKANES, AND CARBONYL YLIDES
Hiroyuki Suga and Kennosuke Itoh
8 CONDENSATION OF PRIMARY NITRO COMPOUNDS TO ISOXAZOLE DERIVATIVES: STOICHIOMETRIC TO CATALYTIC
Francesco De Sarlo and Fabrizio Machetti
9 CARBAMOYLNITRILE OXIDE AND INVERSE ELECTRON-DEMAND 1,3-DIPOLAR CYCLOADDITION
Nagatoshi Nishiwaki and Haruyasu Asahara
PART V [3+2], [3+3], AND [4+2] CYCLOADDITION
10 CYCLOADDITION REACTIONS OF SMALL RINGS
Steven D. R. Christie and Hayley T. A. Watson
PART VI [3+2] AND [5+1] CYCLOADDITION
11 DEVELOPMENT OF NEW METHODS FOR THE CONSTRUCTION OF HETEROCYCLES BASED ON CYCLOADDITION REACTION OF 1,3-DIPOLES
Yutaka Ukaji and Takahiro Soeta
PART VII [3+3] CYCLOADDITION
12 A FORMAL [3þ3] CYCLOADDITION APPROACH TO NATURAL PRODUCT SYNTHESIS
Jun Deng, Xiao-Na Wang, and Richard P. Hsung
PART VIII [4+2] CYCLOADDITION
13 [4þ2] CYCLOADDITION CHEMISTRY OF SUBSTITUTED FURANS 355
Scott Bur and Albert Padwa
14 SYNTHESIS OF SUBSTITUTED OLIGOACENES VIA DIELS-ALDER REACTIONS AND SUBSTITUENT EFFECTS ON MOLECULAR STRUCTURE, PACKING ARRANGEMENT, AND SOLID-STATE OPTICAL PROPERTIES
Chitoshi Kitamura
15 CYCLOREVERSION APPROACH FOR PREPARATION OF LARGE p-CONJUGATED COMPOUNDS
Hidemitsu Uno
PART IX [4+2]/[3+2] CYCLOADDITION
16 TANDEM [4þ2]/[3þ2] CYCLOADDITIONS
Ramil Y. Baiazitov and Scott E. Denmark
PART X [5+1] CYCLOADDITION
17 TRANSITION METAL-CATALYZED OR -MEDIATED [5þ1] CYCLOADDITIONS
Xu-Fei Fu and Zhi-Xiang Yu
PART XI [4+3] CYCLOADDITION
18 [4þ3] CYCLOADDITIONS OF ENOLSILANE DERIVATIVES
Sarah Y. Y. Lam and Pauline Chiu
19 APPLICATION OF THE [4þ3] CYCLOADDITION REACTION TO THE SYNTHESIS OF NATURAL PRODUCTS
Darin E. Jones and Michael Harmata
PART XII [5+2] CYCLOADDITION
20 RECENT DEVELOPMENTS IN THE [5þ2] CYCLOADDITION
Hervé Clavier and Hélène Pellissier